(1R,4R,7S)-1,7-Dimethyl-7-(phenylsulfonylmethyl)spiro[bicyclo[2.2.1]heptane-2,2′-1,3-dioxolane]
نویسندگان
چکیده
منابع مشابه
(1R,4R,7S)-1,7-Dimethyl-7-(phenylsulfonylmethyl)spiro[bicyclo[2.2.1]heptane-2,2′-1,3-dioxolane]
In the title compound, C(18)H(24)O(4)S, the chiral bicyclo-[2.2.1]heptane group is not symmetrical due to the influence of the substituents. The angle between the three-atom bridge plane and the four-atom planes of the boat-shaped six-membered ring are 55.07 (19) and 56.24 (19)°. The bridgehead angle is 92.75 (17)°.
متن کاملCancer Immunity (22 October 2007) Vol. 7, p. 17
1Academic Department of Clinical Oncology, Institute of Infections, Immunity and Inflammation, University of Nottingham, City Hospital, Nottingham, NG5 1PB, United Kingdom 2Dept. of Histopathology, Addenbrooke's NHS Trust, Cambridge, United Kingdom 3Dep. of Histopathology, City Hospital, Nottingham, NG5 1PB, United Kingdom 4Dep. of Pathology, Iran University of Medical Sciences, Tehran, Iran *T...
متن کامل(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarbonitrile
The title compound, C7H8N2O2, formed by dehydration of the corresponding dicarboxamide, crystallizes as rectangular prisms. The mol-ecules have a C 2 axis of symmetry through the C atom bearing the methyl groups and the mid-point of the ring C-C bond, and the 1,3-dioxolane ring adopts the extreme twist conformation of the two possible with this symmetry. This brings the two nitrile groups neare...
متن کاملSynthesis and characterization of 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one
Synthesis and characterization of 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-oneABSTRACTNew 6-(hydroxymethyl)-14, 16-dimethyl-13, 14, 16, 17-tetrahydro-6H-13, 17-epiminodibenzo [e, l] [1, 4] dioxacyclotridecin-15 (7H)-one (2a) was synthesized in good yield by the Petrenko–Kritchenko reaction of 2, 2'-((3-hydroxyp...
متن کاملCancer Immunity (17 August 2007) Vol. 7, p. 13
1027. 27. Brouwers AH, Mulders PF, de Mulder PH, van den Broek WJ, BuijsWC, Mala C, Joosten FB, Oosterwijk E, Boerman OC, Corstens FH,Oyen WJ. Lack of efficacy of two consecutive treatments of radio-immunotherapy with 131I-cG250 in patients with metastasizedclear cell renal cell carcinoma. J Clin Oncol 2005; 23: 6540-6548.(PMID: 16170161) 28. Gleave ME, Elhilali M, Fradet Y,...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2007
ISSN: 1600-5368
DOI: 10.1107/s1600536807058084